In order to control emissions from engine, it is necessary to understand the mixture formation process of diesel spray. In this study, analysis of diesel fuel(n-Tridecane, $C_{13}H_{28}$) spray under a high temperature and pressure was performed by a general-purpose program, ANSYS CFX release 11.0, and the results of these are compared with experimental results of diesel fuel spray using the Exciplex Fluorescence Method. The simulation results of diesel spray is analyzed by using the combination of Large-Eddy Simulation(LES) and Lagrangian Particle Tracking(LPT), and then injection pressure was selected as an analysis parameter. Consequently, it was found that the experimental results and the numerical results are consistent with each other, and then in order to investigate the behavior characteristics of evaporative diesel spray, the effectiveness of the use of CFX of commercial code is definitely validated.