As the environmental regulations is more strengthened, the study of the renewable energy system and waste heat for electricity production is being accelerated. In this study, the performance and power generation rate of solar power generation by using R134a Rankine cycle was analyzed with solar radiation and mass flow rate of R134a. As a result, the maximum and minimum collected heat of solar collector was 20.4 kW and 13.6 kW at October and December, respectively. Besides, the highest generator power was generated at October and it was 0.91 kW/day, while the lowest generator power is occurred at December and it was about 0.85 kW/day.