The surface solar radiation is an important indicators for climate and agricultural research over the Earth system. For the climate and agricultural research, long-term meteorological data and accurate measured data are needed. The daily solar radiation from Jan. 2001 to Dec. 2010 have been employed in this study analyze atmospheric transmissivity for Chupungryeong. The corresponding daily value of atmospheric transmissivity is calculated for Chupungryeong meteorological data. In this paper, relationship analysis of daily solar radiation and atmospheric transmissivity is presented. It shows that atmospheric transmissivity over late December peaked in the 2000s, substantially decreased from the early-January, and changed little after that in summer. Reduction of solar radiation caused a reduction of more than 0.3 in atmospheric transmissivity during July to August. It was concluded that the atmospheric transmissivity could be very useful for evaluating solar radiation. Atmospheric transmissivity approach is suitable for daily-term simulation studies and useful for computing solar radiation.