- Ag-Cu/$Al_2O_3$ 복합촉매를 이용한 저온에서의 $NH_3$ 산화
- ㆍ 저자명
- 임윤희,이주열,박병현,Lim. Yun-Hui,Lee. Ju-Yeol,Park. Byung-Hyun
- ㆍ 간행물명
- 한국유화학회지
- ㆍ 권/호정보
- 2014년|31권 2호|pp.313-319 (7 pages)
- ㆍ 발행정보
- 한국유화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
This study was performed to obtain high conversion efficiency of $NH_3$ and minimize generation of nitrogen oxides using metal-supported catalyst with Ag : Cu ratio. Through structural analysis of the prepared catalyst with Ag : Cu ratio ((10-x)Ag-xCu ($0{leq}x{leq}6$)), it was confirmed that the specific surface area was decrease with increasing metal content. A prepared catalysts showed Type II adsorption isotherms regardless of the ratio Ag : Cu of metal content, and crystalline phase of $Ag_2O$, CuO and $CuAl_2O$ was observed by XRD analysis. In the low temperature($150{sim}200^{circ}C$), a conversion efficiency of AC_10 recorded the highest(98%), whereas AC_5 (Ag : Cu = 5 : 5) also showed good conversion efficiency(93.8%). However, in the high temperature range, the amounts of by-products(NO, $NO_2$) formed with AC_5 was lower than that of AC_10. From these results, It is concluded that AC_5 is more environmentally and economically suitable.