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Absorption of SO2 at High Temperatures by Ionic Liquids and the Absorption Mechanism
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  • Absorption of SO2 at High Temperatures by Ionic Liquids and the Absorption Mechanism
  • Absorption of SO2 at High Temperatures by Ionic Liquids and the Absorption Mechanism
저자명
Tian. Shidong,Hou. Yucui,Wu. Weize,Ren. Shuhang,Qian. Jianguo
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2014년|35권 9호|pp.2791-2796 (6 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The capture of $SO_2$ at or close to the temperatures of real flue gas is much more attractive in application. In this work, two kinds of ionic liquids (ILs) based on lactate anion were used to absorb $SO_2$ at high temperatures from 100 to $120^{circ}C$. The ILs show high absorption capacities of over one mol $SO_2$ per mol IL at $110^{circ}C$. The absorption of $SO_2$ by the ILs based on lactate anion is reversible and the ILs can be reused for the capture of $SO_2$ at high temperatures with high absorption capacity and thermal stability. Furthermore, the absorption mechanism of $SO_2$ by the ILs was studied by FT-IR, $^1H$ NMR and $^{13}C$ NMR spectra. It has been found that there are strong chemical interactions between the ILs and $SO_2$. Also the absorption mechanism is different when there is water present in ILs compared to when there is not.