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Synthesis of Core@shell Structured CuFeS2@TiO2 Magnetic Nanomaterial and Its Application for Hydrogen Production by Methanol Aqueous Solution Photosplitting
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  • Synthesis of Core@shell Structured CuFeS2@TiO2 Magnetic Nanomaterial and Its Application for Hydrogen Production by Methanol Aqueous Solution Photosplitting
  • Synthesis of Core@shell Structured CuFeS2@TiO2 Magnetic Nanomaterial and Its Application for Hydrogen Production by Methanol Aqueous Solution Photosplitting
저자명
Kang. Sora,Kwak. Byeong Sub,Park. Minkyu,Jeong. Kyung Mi,Park. Sun-Min,Kang. Misook
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2014년|35권 9호|pp.2813-2817 (5 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A new magnetic semiconductor material was synthesized to enable separation after a liquid-type photocatalysis process. Core@shell-structured $CuFeS_2@TiO_2$ magnetic nanoparticles were prepared by a combination of solvothermal and wet-impregnation methods for photocatalysis applications. The materials obtained were characterized using X-ray diffraction, transmission electron microscopy, ultraviolet-visible, photoluminescence spectroscopy, Brunauer-Emmett-Teller surface area measurements, and cyclic voltammetry. This study confirmed that the light absorption of $CuFeS_2$ was shifted significantly to the visible wavelength compared to pure $TiO_2$. Moreover, the resulting hydrogen production from the photo-splitting methanol/water solution after 10 hours was more than 4 times on the core@shell structured $CuFeS_2@TiO_2$ nanocatalyst than on either pure $TiO_2$ or $CuFeS_2$.