In this study, characteristics of gaseous pollutants and particulate matter were investigated on the condition of DPF regeneration and normal DPF condition. THC, CO, $CO_2$, NOx, and $CH_4$ were analyzed by MEXA-7200H and CVS-7100 respectively. Particulate Matter (PM) was measured by difference in weight of Membrane filter. Particle Number (PN) was measured by CPC analyzer. And Sulfate, Nitrate, Organic were measured by Aerosol Mass Spectrometer (AMS). As a result, gaseous pollutants and particulate matter were detected in higher concentration during DPF regeneration than normal DPF condition. And the PN increased by 94%, the fuel consumption was reduced by 29% on DPF generation process. Sulfate, Nitrate and Organic were undetectable level during normal DPF condition. But the highest concentration of Sulfate, Nitrate and Organic were measured as $100{mu}g/m^3$, $20{mu}g/m^3$ and $15{mu}g/m^3$ respectively on DPF regeneration condition. VOCs concentrations (Benzene, Toluene, Ethylbenzene, Xylene) were analyzed by using PTR-MS. Benzene and Toluene emission have little or no change depending on DPF regeneration. But the Ethylbenzene and Xylene have comparatively low emissions on DPF regeneration.