The purpose of this research is to extract spectral reflectance characteristics of concretes through basic experiment on concrete specimens and site experiment on actual concrete structures using a field portable spectrometer and a VNIR hyperspectral sensor. A spectrometer (GER-3700) and a VNIR hyperspectral camera (AisaEagle VNIR Hyperspectral Camera) were utilized for extracting spectral characteristics of concrete specimens. Concretes normally show similar patterns that have correlation above 80%, while the high-strengthened concretes display very different results from the normal-strength concretes. We also made a certain conclusion in the laboratory experiment on concrete specimens that both the spectrometer and the VNIR camera vary in spectral reflectance depending on concrete strengths.