In this paper, we developed a new method to transmit multiple visible light channels in time division mode using the AC power line frequency in order to prevent the crosstalk between adjacent optical signals. Synchronizing pulses are generated from the 220 V power line, and one pulse period is subdivided into several time slots for visible light channels. Each channel transmits data in a predefined time slot without interfering adjacent channels. In experiments, synchronizing pulses with a repetition rate of 240 Hz were generated from the 60 Hz power line, and three VLC channels with a bit rate of 9.6 kbps transmitted data independently using the time slots between synchronizing pulses. This configuration is very useful in constructing time division VLC networks for multiple sensors.