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Template-free Synthesis and Characterization of Spherical Y3Al5O12:Ce3+ (YAG:Ce) Nanoparticles
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  • Template-free Synthesis and Characterization of Spherical Y3Al5O12:Ce3+ (YAG:Ce) Nanoparticles
  • Template-free Synthesis and Characterization of Spherical Y3Al5O12:Ce3+ (YAG:Ce) Nanoparticles
저자명
Kim. Taekeun,Lee. Jin-Kyu
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2014년|35권 10호|pp.2917-2921 (5 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Cerium-activated yttrium aluminate ($Y_3Al_5O_{12}:Ce^{3+}$) exhibiting a garnet structure has been widely utilized in the production of light emitting diodes (LEDs) as a yellow emitting phosphor. The commercialized yttrium aluminum garnet (YAG) phosphor is typically synthesized by a solid-state reaction, which produces irregular shape particles with a size of several tens of micrometers by using the top-down method. To control the shape and size of particles, which had been the primary disadvantage of top-down synthetic methods, we synthesized YAG:Ce nanoparticles with a diameter of 500 nm using a coprecipitation method under the atmospheric pressure without the use of template or special equipment. The precursor particles were formed by refluxing an aqueous solution of the nitrate salts of Y, Al, and Ce, urea, and polyvinylpyrrolidone (55 K) at $100^{circ}C$ for 12 h. YAG:Ce nanoparticles were formed by the calcination of precursor particles at $1100^{circ}C$ for 10 h under atmospheric conditions. The phase identification, microstructure, and photoluminescent properties of the products were evaluated by X-ray powder diffraction, scanning electron microscopy, absorption spectrum and photoluminescence analyses.