We made simultaneous surveys of 22 GHz water and 44 / 95 GHz methanol masers toward 299 high-mass protostellar objects using the Korea VLBI Network (KVN) 21-m telescope. The sources were selected from the catalog of Red MSX Source (RMS) survey. Initial selection of the sample present high-mass protostellar objects in an evolutionary phase prior to ultra-compact HII regions, which have bolometric luminosities > $10^3L_{odot}$ but are not associated with any radio continuum emission. After the follow-up work of ongoing RMS survey, final samples contains 56 sources classified as HII regions. We performed a simultaneous survey of 22 GHz water and 44 GHz methanol masers in 2011 and then conducted a simultaneous survey of 22 GHz water and 44 / 95 GHz methanol masers in 2012. The primary scientific goals of these surveys are to investigate the relationship among the three masers and to explore the relationship between each maser and the central star or the parental dense core. The detection rates of two epochs are 42% and 38% for water, 25% and 26% for 44 GHz methanol, and 23% (2012 only) for 95 GHz methanol masers. We performed a statistical analysis on subsample associated with a large data found in literature. In this poster, we will the preliminary data analysis results and discuss the implications.