Plastic mechanism analysis of structures subjected to large deformation has long been used in order to determine collapse mechanisms of steel structures, and the energy absorbed in plastic deformation during such collapses. In this paper the technique is applied to vehicle roof structures that undergo large plastic deformation as a result of rollover crashes. The components of such roof structures are typically steel spot-welded hat-type sections. Ten different deformation mechanisms are defined from investigations of real-world rollover crashes, and an analytical technique to determine the plastic collapse load and energy absorption of such mechanisms is determined. The procedure is presented in a generic manner, such that it may be applied to any vehicle structure undergoing a rollover induced collapse. The procedure is applied to an exemplar vehicle, in order to demonstrate its application in determining the energy absorbed in the deformation of the identified collapse mechanisms. The procedure will be useful to forensic crash reconstructionists, in order to accurately determine the initial travel velocity of a vehicle that has undergone a rollover and for which the post-crash vehicle deformation is known. It may also be used to perform analytical studies of the collapse resistance of vehicle roof structures for optimisation purposes, which is also demonstrated with an analysis of the effect of varying the geometric and material properties of the roof structure components of the exemplar vehicle.