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RGB Light Emissions from ZnSe Based Nanocrystals: ZnSe, ZnSe:Cu, and ZnSe:Mn
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  • RGB Light Emissions from ZnSe Based Nanocrystals: ZnSe, ZnSe:Cu, and ZnSe:Mn
  • RGB Light Emissions from ZnSe Based Nanocrystals: ZnSe, ZnSe:Cu, and ZnSe:Mn
저자명
Song. Byungkwan,Heo. Jeongho,Hwang. Cheong-Soo
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2014년|35권 12호|pp.3601-3608 (8 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

RGB light emitting ZnSe based nanocrystals: ZnSe (blue), ZnSe:Cu (green) and ZnSe:Mn (red) were synthesized by capping the surface of the nanocrystals with oleic acid. The obtained nanocrystal powders were characterized by using XRD, HR-TEM, ICP-AES, FT-IR, and FT-Raman spectroscopies. The optical properties were also measured by UV/Vis and photoluminescence (PL) spectroscopies. The PL spectra showed broad emission peaks at 471 nm (ZnSe), 530 nm (ZnSe:Cu) and 665 nm (ZnSe:Mn), with relative PL efficiencies in the range of 0.7% to 5.1% compared to a reference organic dye standard. The measured average particle sizes from the HR-TEM images for those three nanocrystals were 4.5 nm on average, which were also supported well by the Debye-Scherrer calculations. The elemental compositions of the ZnSe based nanocrystals were determined by ICP-AES analyses. Finally, the drawn CIE diagram showed the color coordinates of (0.15, 0.16) for ZnSe, (0.22, 0.57) for ZnSe:Cu, and (0.62, 0.35) for ZnSe:Mn respectively, which were fairly well matched to that of the RGB color standards.