기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
Novel reforming of pyrolized fuel oil by electron beam radiation for pitch production
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • Novel reforming of pyrolized fuel oil by electron beam radiation for pitch production
저자명
Jin-Young Jung, Mi-Seon Park, Min Il Kim and Young-Seak Lee
간행물명
Carbon LettersKCI
권/호정보
2014년|15권 4호(통권58호)|pp.262-267 (6 pages)
발행정보
한국탄소학회|한국
파일정보
정기간행물|ENG|
PDF텍스트(13.22MB)
주제분야
자연과학
서지반출

영문초록

Pyrolized fuel oil (PFO) was reformed by novel electron beam (E-beam) radiation, and the elemental composition, chemical bonds, average molecular weight, solubility, softening point, yields, and density of the modified patches were characterized. These properties of modified pitch were dependent on the reforming method (heat or E-beam radiation treatment) and absorbed dose. Aromaticity (Fa), average molecular weight, solubility, softening point, and density increased in proportion to the absorbed dose of E-beam radiation, with the exception of the highest absorbed dose, due to modification by free radical polymerization and the powerful energy intensity of E-beam treatment. The H/C ratio and yield exhibited the opposite trend for the same reason. These results indicate that novel E-beam radiation reforming is suitable for the preparation of aromatic pitch with a high β-resin content.

목차

1. Introduction
2. Experimental
3. Results and Discussion
4. Conclusions
Acknowledgements
References

참고문헌 (26건)

  • Greinke RA, O'Connor LH. Determination of molecular weight distributions of polymerized petroleum pitch by gel permeation chromatography with quinoline eluent. Anal Chem, 52, 1877 (1980). http://dx.doi.org/10.1021/ac50062a023.
  • Mora E, Blanco C, Santamarı́a R, Granda M, Menéndez R. A novel method to obtain a petroleum-derived mesophase pitch suitable as carbon fibre precursor. Carbon, 41, 445 (2003). http://dx.doi.org/10.1016/S0008-6223(02)00354-8.
  • Dong W, Liu HC, Park SJ, Jin FL. Fracture toughness improvement of epoxy resins with short carbon fibers. J Ind Eng Chem, 20, 1220 (2014). http://dx.doi.org/10.1016/j.jiec.2013.06.053.
  • Mohammadi S, Afshar Taromi F, Shariatpanahi H, Neshati J, Hemmati M. Electrochemical and anticorrosion behavior of functionalized graphite nanoplatelets epoxy coating. J Ind Eng Chem, 20,4124 (2014). http://dx.doi.org/10.1016/j.jiec.2014.01.011.
  • Greinke RA. Kinetics of petroleum pitch polymerization by gel permeation chromatography. Carbon, 24, 677 (1986). http://dx.doi. org/10.1016/0008-6223(86)90175-2.
  • Edwards WF, Jin L, Thies MC. MALDI-TOF mass spectrometry: obtaining reliable mass spectra for insoluble carbonaceous pitches. Carbon, 41, 2761 (2003). http://dx.doi.org/10.1016/S0008-6223(03)00386-5.
  • Mayani VJ, Mayani SV, Lee Y, Park SK. A non-chromatographic method for the separation of highly pure naphthalene crystals from pyrolysis fuel oil. Sep Purif Technol, 80, 90 (2011). http://dx.doi.org/10.1016/j.seppur.2011.04.013.
  • Alcañiz-Monge J, Cazorla-Amorós D, Linares-Solano A, Oya A, Sakamoto A, Hosm K. Preparation of general purpose carbon fibers from coal tar pitches with low softening point. Carbon, 35, 1079 (1997). http://dx.doi.org/10.1016/S0008-6223(97)00064-X.
  • Lewis IC. Thermal polymerization of aromatic hydrocarbons. Carbon, 18, 191 (1980). http://dx.doi.org/10.1016/0008-6223(80)90060-3.
  • Menéndez R, Granda M, Fernández JJ, Figueiras A, Bermejo J, Bonhomme J, Belzunce J. Influence of pitch air-blowing and thermal treatment on the microstructure and mechanical properties of carbon/carbon composites. J Microsc, 185, 145 (1997). http://dx.doi.
  • Vautard F, Ozcan S, Poland L, Nardin M, Meyer H. Influence of thermal history on the mechanical properties of carbon fiber–acrylate composites cured by electron beam and thermal processes. Composites A, 45, 162 (2013). http://dx.doi.org/10.1016/j.composite
  • Schlemmer B, Bandari R, Rosenkranz L, Buchmeiser MR. Electron beam triggered, free radical polymerization-derived monolithic capillary columns for high-performance liquid chromatography. J Chromatogr A, 1216, 2664 (2009). http://dx.doi.org/10.1016/j.chroma
  • Hwang JS, Lee CH, Cho KH, Kim MS, Kim CJ, Ryu SK, Rhee BS. Preparation of anisotropic/isotropic pitches from NCC-PFO. J Korean Inst Chem Eng, 33, 551 (1995).
  • Chiono V, Carmagnola I, Gentile P, Boccafoschi F, Tonda-Turo C, Ballarini M, Georgieva V, Georgiev G, Ciardelli G. Layer-by-layer coating of photoactive polymers for biomedical applications. Surf Coat Technol, 206, 2446 (2012). http://dx.doi.org/10.1016/j.
  • Wazir AH, Kakakhel L. Preparation and characterization of pitchbased carbon fibers. New Carbon Mater, 24, 83 (2009). http://dx.doi.org/10.1016/S1872-5805(08)60039-6.
  • Bayar Ş, Dinçer HA, Gonca E. The synthesis of some phthalocyanines derived from bulky substituted phthalonitriles. Dyes Pigments, 80, 156 (2009). http://dx.doi.org/10.1016/j.dyepig.2008.06.006.
  • Heavy Oil Division, Refining Section of the Japan. Characterization of heavy oils and its application: an introduction. J Japan Petrol Inst, 24, 43 (1981). http://dx.doi.org/10.1627/jpi1958.24.43
  • Yamada Y, Honda H, Abe T. Production of binder pitch from petroleum vacuum residue (part 1): relations between the properties of pitch obtained and heat-treatment conditions of vacuum residue. J Japan Petrol Inst, 18, 758 (1975). http://dx.doi.org/10.1627/
  • Musil J, Zatloukal M. Experimental investigation of flow induced molecular weight fractionation phenomenon for two linear HDPE polymer melts having same Mn and Mw but different Mz and Mz+1 average molecular weights. Chem Eng Sci, 81, 146 (2012). http://dx.
  • Botman JIM, Derksen ATAM, van Herk AM, Jung M, Kuchta FD, Manders LG, Timmermans CJ, de Voigt MJA. A linear accelerator as a tool for investigations into free radical polymerization kinetics and mechanisms by means of pulsed electron beam polymerization. N
  • Kershaw JR, Black KJT. Structural characterization of coal-tarand petroleum pitches. Energy Fuels, 7, 420 (1993). http://dx.doi.org/10.1021/ef00039a014.
  • Kim JH, Lee SH, Lee YS. Preparation of pitch for melt-electrospinning from naphtha cracking bottom oil. Appl Chem Eng, 24, 402 (2013).
  • Xu Y, Wang M, Ge X. The characterization of latex particles prepared by pulsed electron beam induced emulsion polymerization. Radiat Phys Chem, 81, 1634 (2012). http://dx.doi.org/10.1016/j.radphyschem.2012.05.001.
  • Oshida K, Bonnamy S. Primary carbonization of an anisotropic ‘mesophase’ pitch compared to conventional isotropic pitch. Carbon, 40, 2699 (2002). http://dx.doi.org/10.1016/S0008-6223(02)00184-7.
  • Zha QF, Shi JL, Ji Y, Liu L, Qian SA. The effect of composition and process variables on the spinnability of mesophase pitch. Carbon, 30, 739 (1992). http://dx.doi.org/10.1016/0008-6223(92)90156-Q.
  • Jung IH, Lee MJ, Mah YJ. Decomposition of PCBs in transformer oil using an electron beam accelerator. Radiat Phys Chem, 81, 899(2012). http://dx.doi.org/10.1016/j.radphyschem.2011.12.042.
구매하기 (3,000)
추천 연관논문