기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
Preparation and thermal properties of polyethylene-based carbonized fibers
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • Preparation and thermal properties of polyethylene-based carbonized fibers
저자명
Kwan-Woo Kim, Hye-min Lee, Byoung Suhk Kim, Seon-Hwan Hwang, Lee-Ku Kwac, Kay-Hyeok An and Byung-Joo Kim
간행물명
Carbon LettersKCI
권/호정보
2015년|16권 1호(통권59호)|pp.62-66 (5 pages)
발행정보
한국탄소학회|한국
파일정보
정기간행물|ENG|
PDF텍스트(1.46MB)
주제분야
자연과학
서지반출

영문초록

In this study, carbonized fibers were prepared by using acidically cross-linked LDPE fibers. The surface morphologies of the carbonized fibers were observed by SEM. The effects of cross-linking process temperatures were studied using thermal analyses such as DSC and TGA. The melting and heating enthalpy of the fibers decreased as the cross-linking temperature increased. The cross-linked fibers had a carbonization yield of over 50%. From SEM results the highest yield of carbonized LDPE-based fibers was obtained by cross-linking at a sulfate temperature (170oC). As a result, carbonation yield of the carbonized fibers was found to depend on the functions of the cross-linking ratio of the LDPE precursors.

목차

1. Introduction
2. Experiment Details
3. Results and Discussion
4. Conclusion
Acknowledgments
References

참고문헌 (27건)

  • Fitzer E. Pan-based carbon fibers-present state and trend of the technology from the viewpoint of possibilities and limits to influence and to control the fiber properties by the process parameters. Carbon, 27, 621 (1989).
  • Park SJ. Kim BJ. Carbon fibers and their composites. Springer Seri Mater Sci, 210, 275 (2015).
  • Kim SY. Kim SY. Lee SH. Jo SM. Im YH. Microwave plasma carbonization for the fabrication of polyacrylonitrile-based carbon fiber. Polymer, in press (2014).
  • Rahaman MSA. Ismail AF. Mustafa A. A review of heat treatment on polyacrylonitrile fiber. Polym Degrad Stab, 92, 1421 (2007).
  • Edie DD. The effect of processing on the structure and properties of carbon fibers. Carbon, 36, 345 (1998).
  • Deng W. Lobovsky A. Iacono S. Wu T. Tomar N. Budy SM. Long T. Hoffman WP. Smith JDW. Poly (acrylonitrile – co -1 –vinylimidazole): A new melt processable carbon fiber precursor. Polymer, 52, 622 (2011).
  • Kim KS. Shim YS. Kim BJ. Meng LY. Lee SY. Park SJ. Present status and applications of carbon fibers-reinforced composites for aircrafts. Carbon Lett, 11, 235 (2010).
  • Baker DA. Gallego NC. Baker FS. On the characterization and spinning of an Organic-purified lignin toward the manufacture of low-cost carbon fiber. J Appl Polym Sci, 124, 227 (2012).
  • Ismail AF. Yusof N. Post spinning and pyrolysis processes of polyacrylonitrile (PAN)-based carbon fiber and activated carbon fiber: A review. J Anal Appl Pyrol, 93, 1 (2012).
  • Huang X. Fabrication and properties of carbon fibers. Materials, 2, 2369 (2009).
  • Sutasinpromprae J. Jitjaicham S. Nithitanakul M. Meechaisue C. Supaphol P. Preparation and characterization of ultrafine electrospun polyacrylonitrile fibers and their subsequent pyrolysis to carbon fibers. Polymer. Int, 55, 825 (2006).
  • Jie L. Wangxi Z. Structural changes during the thermal stabilization of modified and original polyacrylonitrile precursors. J Appl Polym Sci, 97, 2047 (2005).
  • Kadla JF. Kubo S. Venditti RA. Gilbert RD. Compere AL. Griffith W. Lignin-based carbon fibers for composite fiber applications. Carbon, 40, 2913 (2002).
  • Zhang WX. Wang YZ. Manufacture of carbon fibers from polyacrylonitrile precursors treated with CoSO4. J Appl Polym Sci, 85, 123 (2002).
  • Maradur SP. Kim CH. Kim SY. Kim BH. Kim WC. Preparation of carbon fibers from a lignin copolymer with polyacylonitrile. Synth Met, 162, 453 (2012).
  • Baker DA. Gallego NC. Baker FS. Lignin-based activated carbon fibers and controllable pore size and properties. J Appl Polym Sci, 121, 989 (2011).
  • Ibrahim MNM. Ahmed-Haras MR. Sipaut CS. Aboul-Enein HY Mohamed AA. Preparation and characterization of a newly water soluble lignin graft copolymer from oil palm lignocellulosic waste. Carbohydr Polym, 80, 1102 (2010).
  • Baker DA. Rials TG. Recent advances in low-cost carbon fiber manufacture from lignin. J Appl Polym Sci, 130, 713 (2013).
  • Math F. Marianneau G. A new method for manufacturing carbonfibre microelectrodes. J Neurosci Methods, 52, 149 (1994).
  • Parent JS. Hyslop DK. Dynamics and yields of AOTEMPO-mediated polyolefin cross-linking. Polymer, 54, 84 (2013).
  • Camara S. Gilbert BC. Meier RJ. Duin MV. Whitwood AC. EPR studies of peroxide decomposition, radical formation and reactions relevant to cross-linking and grafting in polyolefins. Polymer, 47, 4683 (2006).
  • Yi Z. Pan L. Li YG. Li YS. Synthesis and characterisation of novel functional polyolefin containing sulfonic acid groups. Eu Polym J, 44, 475 (2008).
  • Sirisinha K. Boonkongkaew M. Kositchaiyoug S. The effect of silane carriers on silane grafting of high-density polyethylene and properties of crosslinked products. Polym Test, 29, 958 (2010).
  • Postema AR. Groot DH. Pennings AJ. Amorphous carbon fibres from linear low density polyethylene. J Mater Sci, 25, 4216 (1990).
  • Zhang D. Sun Q. Structure and properties development during the conversion of polyethylene precursors to carbon fibers. J Appl Polym Sci, 62, 367 (1996).
  • Penning JP. Lagcher R. Pennings AJ. The effect of diameter on the mechanical properties of amorphous carbon fibres from linear low density polyethylene. Polym Bull, 25, 405 (1991).
  • Ihate J. Formation and reaction of polyenesulfonic acid. I. reaction of polyethylene films with SO3. J Polym Sci Part A: Polym Chem, 26, 167 (1988).
구매하기 (1,500)
추천 연관논문