Two pitches with different average molecular structures were electrospun and compared in
terms of the properties of their fibers after oxidative stabilization, carbonization, and activation.
The precursor with a higher molecular weight and greater content of aliphatic groups
(Pitch A) resulted in better solubility and spinnability compared to that with a lower molecular
weight and lower aliphatic group content (Pitch B). The electrical conductivity of the
carbon fiber web from Pitch A of 67 S/cm was higher than that from Pitch B of 52 S/cm. The
carbon fiber web based on Pitch A was activated more readily with lower activation energy,
resulting in a higher specific surface area compared to the carbon fiber based on Pitch B
(Pitch A, 2053 m2/g; Pitch B, 1374 m2/g).
Key words: pitch, electrospinning, carbon fiber, spinnability, molecular structure, activation