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Bulk graphite: materials and manufacturing process
Sang-Min Lee, Dong-Su Kang and Jea-Seung Roh 한국탄소학회 Carbon Letters 12 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 1 135-146 (12 pages)
Graphite can be classified into natural graphite from mines and artificial graphite. Due to its outstanding properties such as light weight, thermal resistance, electrical conductivity, thermal conductivity, chemical stability, and high-temperature strength, artificial graphite is used across various industries in powder form and bulk form. Artificial graphite of powder form is usually used as anode materials for secondary cells, while artificial graphite of bulk form is used in steelmaking... -
Stabilization of pitch-based carbon fibers accompanying electron beam irradiation and their mechanical properties
Mi-Seon Park, Yoonyoung Ko, Min-Jung Jung, Young-Seak Lee 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 8 121-126 (6 pages)
Carbon fibers are prepared by stabilizing pitch fibers accompanying electron beam (E-beam) irradiation. The carbon fibers pretreated by E-beam irradiation achieve a higher stabilization index than the carbon fibers that are only heat-stabilized. In addition, the carbon fibers subjected to E-beam irradiation in the stabilization step exhibit a comparable tensile strength to that of general purpose carbon fibers. The carbon fibers pretreated with an absorbed dose of 3000 kGy have a tensile... -
Preparation and characterization of carbon fiber-reinforced thermosetting composites: a review
Fan-Long Jin, Soo-Jin Park 한국탄소학회 Carbon Letters 11 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 1 67-77 (11 pages)
Carbon fibers (CFs) have a unique combination of properties which allow them to be widely used as reinforcing materials in advanced polymer composites. The mechanical properties of CF-reinforced polymer composites are governed mainly by the quality of interfacial adhesion between the CFs and the polymer matrix. Surface treatments of CFs are generally carried out to introduce chemical functional groups on the fiber surfaces, which provide the ability to control the surface characteristics of CFs.... -
Conducting and interface characterization of carbonate-type organic electrolytes containing EMImBF4 as an additive against activated carbon electrode
Mingyeong Kim, Kyungmin Kim and Seok Kim 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 8 51-56 (6 pages)
Carbonate-type organic electrolytes were prepared using propylene carbonate (PC) and dimethyl carbonate (DMC) as a solvent, quaternary ammonium salts, and by adding different contents of 1-ethyl-3-methyl imidazolium tetrafluoroborate (EMImBF4). Cyclic voltammetry and linear sweep voltammetry were performed to analyze conducting behaviors. The surface characterizations were analyzed by scanning electron microscopy method and X-ray photoelectron spectroscopy. From the experimental results,... -
An overview of new oxidation methods for polyacrylonitrile?based carbon fibers
Hye Kyoung Shin, Mira Park, Hak-Yong Kim and Soo-Jin Park 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 2 11-18 (8 pages)
The process of oxidizing polyacrylonitrile (PAN)-based carbon fibers converts them into an infusible and non-flammable state prior to carbonization. This represents one of the most important stages in determining the mechanical properties of the final carbon fibers, but the most commonly used methods, such as thermal treatment (200°C to 300°C), tend to waste a great deal of process time, money, and energy. There is therefore a need to develop more advanced oxidation methods for PAN precursor... -
Effects of comonomer with carboxylic group on stabilization of high molecular weight polyacrylonitrile nanofibrous copolymers
Danyun Lei, Kesavan Devarayan1, Xiang-Dan Li, Woong-Ki Choi, Min-Kang Seo and Byoung-Suhk Kim 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 9 290-294 (5 pages)
New precursors, poly(acrylonitrile-co-crotonic acid) (poly(AN-CA)) and poly(acrylonitrile-co-itaconic acid-co-crotonic acid) (poly(AN-IA-CA)) copolymers, for the preparation of carbon fibers, were explored in this study. The effects of comonomers with acidic groups, such as crotonic acid (CA) and/or itaconic acid (IA), on the stabilization of nanofibrous polyacrylonitrile (PAN) copolymers were studied. The extent of stabilization, evaluated by Fourier transform infrared spectroscopy, revealed... -
Novel reforming of pyrolized fuel oil by electron beam radiation for pitch production
Jin-Young Jung, Mi-Seon Park, Min Il Kim and Young-Seak Lee 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 5 262-267 (6 pages)
Aromaticity (Fa), average molecular weight, solubility, softening point, and density increased in proportion to the absorbed dose of E-beam radiation, with the exception of the highest absorbed dose, due to modification by free radical polymerization and the powerful energy intensity of E-beam treatment. The H/C ratio and yield exhibited the opposite trend for the same reason. These results indicate that novel E-beam radiation reforming is suitable for the preparation of aromatic pitch with a... -
Modification of isotropic coal-tar pitch by acid treatments for carbon fiber melt-spinning
Mi Jung Yoo, Hyo Jun Ko, Yun-Soo Lim and Myung-Soo Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 3 247-254 (8 pages)
In this work, thermal treatment accompanied with different acid treatments was applied to a commercial coal tar pitch (CTP) to obtain a spinnable precursor pitch for carbon fiber. In the case of thermal treatment only, a relatively high reaction temperature of between 380°C and 400°C was required to obtain a softening point (SP) range of 220°C-260°C and many meso-phase particles were created during the application of high reaction temperature. When nitric acid or sulfuric acid treatment was... -
Influence of ionic liquid additives on the conducting and interfacial properties of organic solvent-based electrolytes against an activated carbon electrode
Kyungmin Kim, Yongju Jung, Seok Kim 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 5 187-191 (5 pages)
This study reports on the influence of N-butyl-N-methylpyrrolidinium tetrafluoroborate (PYR14BF4) ionic liquid additive on the conducting and interfacial properties of organic solvent based electrolytes against a carbon electrode. We used the mixture of ethylene carbonate/dimethoxyethane (1:1) as an organic solvent electrolyte and tetraethylammonium tetrafluoroborate (TEABF4) as a common salt. Using the PYR14BF ionic liquid as additive produced higher ionic conductivity in the electrolyte and... -
Enhanced electrocapacitive performance and high power density of polypyrrole/graphene oxide nanocomposites prepared at reduced temperature
Harish Mudila, Varsha Joshi, Sweta Rana, Mohmd. Ghulam Haider Zaidi, Sarfaraz Alam 한국탄소학회 Carbon Letters 9 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 3 171-179 (9 pages)
by the cetyltrimethylammonium bromide-assisted dilute-solution polymerization of pyrrole in presence of GO (wt%) ranging from 1.0 to 4.0 with ferric chloride as an oxidant. The formation of the PNCs was ascertained through Fourier-transform infrared spectrometry, X-ray diffraction spectra, scanning electron microscopy and simultaneous thermogravimetric-differential scanning calorimetry. The electrocapacitive performance of the electrodes derived from sulphonated polysulphone-bound PNCs was...


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