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Catalytic activity and controllable deposition of platinum nanoparticles on ionic polymer-functionalized graphene as catalysts for direct methanol fuel cells
Jiyoung Park, Changyoon Song, Qizhong Sun, Yongju Jung, Seok Kim 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.4 6 260-264 (5 pages)
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Photocatalytic performance of graphene/Ag/TiO₂ hybrid nanocomposites
Jong-Ho Lee, In-Ki Kim, Donghwan Cho, Jeong-Il Youn, Young-Jig Kim, Han-Jun Oh 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.4 4 247-254 (8 pages)
To improve photocatalytic efficiency, graphene/Ag/TiO₂ nanotube catalyst was synthesized, and its surface characteristics and photocatalytic activity investigated. For deposition of Ag nanoparticles on the TiO₂ nanotubes, a polymer compound containing CH₃COOAg/poly(Llactide) was utilized, and the silver particles were precipitated by reducing the silver ions during the annealing process. Graphene deposition on the Ag/TiO₂ nanotubes was achieved using an electrophoretic deposition process.... -
Electrochemical synthesis of nanosized hydroxyapatite/graphene composite powder
Vesna Mi?kovi?-Stankovi?, Sanja Erakovi?, Ana Jankovi?, Maja Vuka?inovi?-Sekuli?, Miodrag Mitri?, Young Chan Jung, Soo Jin Park, Kyong 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.4 2 233-240 (8 pages)
Electrochemical synthesis was employed to prepare a novel hydroxyapatite/graphene (HAP/ Gr) composite powder suitable for medical applications as a hard tissue implant (scaffold). The synthesis was performed in a homogeneous dispersion containing Na2H2EDTA·2H2O, NaH2PO4 and CaCl2 with a Ca/EDTA/PO4 3? concentration ratio of 0.25/0.25/0.15M, along with 0.01 wt% added graphene nanosheets, at a current density of 137 mA cm?2 and pH value of 9.0. The field emission scanning electron microscopy and... -
Influence of defective sites in Pt/C catalysts on the anode of direct methanol fuel cell and their role in CO poisoning: a first-principles study
Soonchul Kwon, Seung Geol Lee 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 6 198-202 (5 pages)
defect adsorption sites on the anode of direct methanol fuel cells were investigated, to elucidate the mechanisms of H2 dissociation and carbon monoxide (CO) poisoning. Density functional theory calculations were carried out to determine the effect of defect sites located neighboring to or distant from the Pt catalyst on H2 and CO adsorption properties, based on electronic properties such as adsorption energy and electronic band gap. Interestingly, the presence of neighboring defect sites led to... -
Molecular approach to hexagonal and cubic diamond nanocrystals
Mudar Ahmed Abdulsattar 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 5 192-197 (6 pages)
magnetic resonance and ultraviolet-visible spectra are investigated to identify the main spectroscopic differences between hexagonal and cubic structures at the molecular and nanoscale. Natural bond orbital population analysis shows that the bonding of the present wurtzoids and diamondoids differs from ideal sp3 bonding. The bonding for carbon valence orbitals is in the range (2s0.982p3.213p0.02)-(2s0.942p3.313p0.02) for wurtzoid and (2s0.932p3.293p0.01)-(2s0.992p3.443p0.01) for diamantane. -
Nanoporous graphene oxide membrane and its application in molecular sieving
S. Mahmood Fatemi, Masoud Arabieh, Hamid Sepehrian 한국탄소학회 Carbon Letters 9 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 4 183-191 (9 pages)
Gas transport through graphene-derived membranes has gained much interest recently due to its promising potential in filtration and separation applications. In this work, we explore Kr-85 gas radionuclide sequestration from natural air in nanoporous graphene oxide membranes in which different sizes and geometries of pores were modeled on the graphene oxide sheet. This was done using atomistic simulations considering mean-squared displacement, diffusion coefficient, number of crossed species of... -
Mesophase formation behavior in petroleum residues
Subhash Kumar, Manoj Srivastava 한국탄소학회 Carbon Letters 12 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 3 171-182 (12 pages)
a wide spectrum of industrial and advanced carbon products. It is produced by pyrolysis of petroleum residues. In this work, mesophase formation behavior in petroleum residues was studied to prepare environmentally- benign mesophase pitches, and the composition of petroleum residues and its influence on the mesophase formation was investigated. Two petroleum residues, i.e., clarified oil s (CLO-1, CLO-2) obtained from fluid catalytic cracking units of different Indian petroleum refineries, were... -
Changes in the porosity of bulk graphite according to the viscosity of resin for impregnation
Sang-Min Lee, Dong-Su Kang, Hye-Sung Kim, Jea-Seung Roh 한국탄소학회 Carbon Letters 3 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 10 132-134 (3 pages)
When manufacturing bulk graphite, pores develop within the bulk during the carbonization process due to the volatile components of the fillers and the binders. As a result, the physical properties of bulk graphite are inferior to the theoretical values. Impregnants are impregnated into the pores generated in the carbonization process through pressurization and/or depressurization. The physical properties of bulk graphite that has undergone impregnation and re-carbonization processes are... -
Mechanisms of Na adsorption on graphene and graphene oxide: density functional theory approach
Hye Sook Moon, Ji Hye Lee, Soonchul Kwon, Il Tae Kim, Seung Geol Lee 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 7 116-120 (5 pages)
We investigated the adsorption of Na on graphene and graphene oxide, which are used as anode materials in sodium ion batteries, using density functional theory. The adsorption energy for Na on graphene was -0.507 eV at the hollow sites, implying that adsorption was favorable. In the case of graphene oxide, Na atoms were separately adsorbed on the epoxide and hydroxyl functional groups. The adsorption of Na on graphene oxide-epoxide (adsorption energy of -1.024 eV) was found to be stronger than...


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