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An overview of new oxidation methods for polyacrylonitrile?based carbon fibers
Hye Kyoung Shin, Mira Park, Hak-Yong Kim and Soo-Jin Park 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 2 11-18 (8 pages)
The process of oxidizing polyacrylonitrile (PAN)-based carbon fibers converts them into an infusible and non-flammable state prior to carbonization. This represents one of the most important stages in determining the mechanical properties of the final carbon fibers, but the most commonly used methods, such as thermal treatment (200°C to 300°C), tend to waste a great deal of process time, money, and energy. There is therefore a need to develop more advanced oxidation methods for PAN precursor... -
Effects of comonomer with carboxylic group on stabilization of high molecular weight polyacrylonitrile nanofibrous copolymers
Danyun Lei, Kesavan Devarayan1, Xiang-Dan Li, Woong-Ki Choi, Min-Kang Seo and Byoung-Suhk Kim 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 9 290-294 (5 pages)
New precursors, poly(acrylonitrile-co-crotonic acid) (poly(AN-CA)) and poly(acrylonitrile-co-itaconic acid-co-crotonic acid) (poly(AN-IA-CA)) copolymers, for the preparation of carbon fibers, were explored in this study. The effects of comonomers with acidic groups, such as crotonic acid (CA) and/or itaconic acid (IA), on the stabilization of nanofibrous polyacrylonitrile (PAN) copolymers were studied. The extent of stabilization, evaluated by Fourier transform infrared spectroscopy, revealed... -
Thermal properties in strong hydrogen bonding systems composed of poly(vinyl alcohol), polyethyleneimine, and graphene oxide
Sua Choi, Duck Kun Hwang and Heon Sang Lee 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 8 282-289 (8 pages)
PEI. These abnormal increases of Tgs may be due to the negative entropy of mixing which is associated with strong hydrogen bonding between PVA and PEI. The degree of depression of s was not reduced by the negative entropy of mixing, since strong hydrogen bonding also causes an increase in the magnitude of negative c between PVA and PEI. The Tg of PVA was increased significantly by adding 0.7 wt.% GO into PVA. The magnitude of negative c was increased by adding GO into the blends of PVA and PEI -
Properties of multi-walled carbon nanotube reinforced epoxy composites fabricated by using sonication and shear mixing
Min Ye Koo, Hon Chung Shin, Won-Seok Kim and Gyo Woo Lee 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 4 255-261 (7 pages)
thermal, and electrical properties of the fabricated specimens were measured and evaluated. From the images and the results of the measurements of tensile strengths, the specimens having 0.6 wt% nanotube content showed better dispersion and higher strength than those of the other specimens. The Young’s moduli of the specimens increased as the nanotube filler content was increased in the matrix. As the concentrations of nanotubes filler were increased in the composite specimens, their storage a... -
Modification of isotropic coal-tar pitch by acid treatments for carbon fiber melt-spinning
Mi Jung Yoo, Hyo Jun Ko, Yun-Soo Lim and Myung-Soo Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 3 247-254 (8 pages)
In this work, thermal treatment accompanied with different acid treatments was applied to a commercial coal tar pitch (CTP) to obtain a spinnable precursor pitch for carbon fiber. In the case of thermal treatment only, a relatively high reaction temperature of between 380°C and 400°C was required to obtain a softening point (SP) range of 220°C-260°C and many meso-phase particles were created during the application of high reaction temperature. When nitric acid or sulfuric acid treatment was... -
Overlook of carbonaceous adsorbents and processing methods for elemental mercury removal
Kyong-Min Bae, Byung-Joo Kim and Soo-Jin Park 한국탄소학회 Carbon Letters 9 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 2 238-246 (9 pages)
People have been concerned about mercury emissions for decades because of the extreme toxicity, persistence, and bioaccumulation of methyl Hg transformed from emitted Hg. This paper presents an overview of research related to mercury control technology and identifies areas requiring additional research and development. It critically reviews measured mercury emissions progress in the development of promising control technologies. This review provides useful information to scientists and engineers... -
Method and mechanism of dispersing agent free dispersion of short carbon fibers in silicon carbide powder
Thakur Sudesh Kumar Raunija, Mariamma Mathew, Sharad Chandra Sharma 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 4 180-186 (7 pages)
This study highlights a novel method and mechanism for the rapid and effective milling of carbon fibers (CFs) in silicon carbide (SiC) powder, and also the dispersion of CFs in SiC powder. The composite powders were prepared by chopping and exfoliation of CFs, and ball milling of CFs and SiC powder in isopropyl alcohol. A wide range of CFs loading, from 10 to 50 vol%, was studied. The milling of CFs and SiC powder was checked by measuring the average particle size of the composite powders. The... -
Pitch based carbon fibers for automotive body and electrodes
Kap Seung Yang, Bo-Hye Kim, Seong-Ho Yoon 한국탄소학회 Carbon Letters 9 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 2 162-170 (9 pages)
They also recommended the use of carbon fiber with strength of 1700 MPa, modulus of 170 GPa, and 1.5% elongation. This study introduced a ca. 5.5 μm carbon fiber with 2000 MPa tensile strength obtained from a precursor through simple distillation of petroleum residue. Petroleum pitch based carbon nanofibers prepared via electrospinning were characterized and potential applications were introduced on the basis of their large specific surface area and relatively high electrical conductivity. -
Fabrication of isotropic bulk graphite using artificial graphite scrap
Sang-Min Lee, Dong-Su Kang, Woo-Seok Kim, Jea-Seung Roh 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 12 142-145 (4 pages)
Isotropic synthetic graphite scrap and phenolic resin were mixed, and the mixed powder was formed at 300 MPa to produce a green body. New bulk graphite was produced by carbonizing the green body at 700°C, and the bulk graphite thus produced was impregnated with resin and re-carbonized at 700°C. The bulk density of the bulk graphite was 1.29 g/cm3, and the porosity of the open pores was 29.8%. After one impregnation, the density increased to 1.44 g/cm3 while the porosity decreased to 25.2%.... -
Facile preparation of self-assembled wool-based graphene hydrogels by electron beam irradiation
Mira Park, Bishweshwar Pant, Jawun Choi, Yong Wan Park, Chohye Lee, Hye Kyoung Shin, Soo-Jin Park4, Hak-Yong Kim 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 11 136-141 (6 pages)
levels of EBI radiation, the highly porous, self-assembled, wool-based graphene hydrogels were characterized using scanning electron microscopy and Fourier-transform infrared spectroscopy; to determine the gel fraction, degree of swelling, gel strength, kinetics-of-swelling analyses and removal of hexavalent chromium (Cr(VI)) from the aqueous solution. X-ray diffraction results confirmed that EBI played a significantly important role in reducing GO to graphene. The adsorption equilibrium of...


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