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Molecular approach to hexagonal and cubic diamond nanocrystals
Mudar Ahmed Abdulsattar 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 5 192-197 (6 pages)
magnetic resonance and ultraviolet-visible spectra are investigated to identify the main spectroscopic differences between hexagonal and cubic structures at the molecular and nanoscale. Natural bond orbital population analysis shows that the bonding of the present wurtzoids and diamondoids differs from ideal sp3 bonding. The bonding for carbon valence orbitals is in the range (2s0.982p3.213p0.02)-(2s0.942p3.313p0.02) for wurtzoid and (2s0.932p3.293p0.01)-(2s0.992p3.443p0.01) for diamantane. -
Mesophase formation behavior in petroleum residues
Subhash Kumar, Manoj Srivastava 한국탄소학회 Carbon Letters 12 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 3 171-182 (12 pages)
Mesophase pitch is an important starting material for making a wide spectrum of industrial and advanced carbon products. It is produced by pyrolysis of petroleum residues. In this work, mesophase formation behavior in petroleum residues was studied to prepare environmentally- benign mesophase pitches, and the composition of petroleum residues and its influence on the mesophase formation was investigated. Two petroleum residues, i.e., clarified oil s (CLO-1, CLO-2) obtained from fluid catalytic... -
Mechanisms of Na adsorption on graphene and graphene oxide: density functional theory approach
Hye Sook Moon, Ji Hye Lee, Soonchul Kwon, Il Tae Kim, Seung Geol Lee 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 7 116-120 (5 pages)
We investigated the adsorption of Na on graphene and graphene oxide, which are used as anode materials in sodium ion batteries, using density functional theory. The adsorption energy for Na on graphene was -0.507 eV at the hollow sites, implying that adsorption was favorable. In the case of graphene oxide, Na atoms were separately adsorbed on the epoxide and hydroxyl functional groups. The adsorption of Na on graphene oxide-epoxide (adsorption energy of -1.024 eV) was found to be stronger than... -
Activated carbons prepared from mixtures of coal tar pitch and petroleum pitch and their electrochemical performance as electrode materials for electric double-layer capacitor
Eunji Lee, Soon Hyung Kwon, Poo Reum Choi, Ji Chul Jung, Myung-Soo Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 2 78-85 (8 pages)
Activated carbons (ACs) were prepared by activation of coal tar pitch (CTP) in the range of 700°C-1000°C for 1-4 h using potassium hydroxide (KOH) powder as the activation agent. The optimal activation conditions were determined to be a CTP/KOH ratio of 1:4, activation temperature of 900°C, and activation time of 3 h. The obtained ACs showed increased pore size distribution in the range of 1 to 2 nm and the highest specific capacitance of 122 F/g in a two-electrode system with an organic... -
Influence of hot-pressing pressure on the densification of short-carbon-fiber-reinforced, randomly oriented carbon/carbon composite
Thakur Sudesh Kumar Raunija and Sharad Chandra Sharma 한국탄소학회 Carbon Letters 9 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 4 25-33 (9 pages)
The prime objective of this research was to study the influence of hot-pressing pressure and matrix-to-reinforcement ratio on the densification of short-carbon-fiber-reinforced, randomly oriented carbon/carbon-composite. Secondary objectives included determination of the physical and mechanical properties of the resulting composite. The ‘hybrid carbon-fiberreinforced mesophase-pitch-derived carbon-matrix’ composite was fabricated by hot pressing. During hot pressing, pressure was varied from 5... -
An overview of new oxidation methods for polyacrylonitrile?based carbon fibers
Hye Kyoung Shin, Mira Park, Hak-Yong Kim and Soo-Jin Park 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 2 11-18 (8 pages)
The process of oxidizing polyacrylonitrile (PAN)-based carbon fibers converts them into an infusible and non-flammable state prior to carbonization. This represents one of the most important stages in determining the mechanical properties of the final carbon fibers, but the most commonly used methods, such as thermal treatment (200°C to 300°C), tend to waste a great deal of process time, money, and energy. There is therefore a need to develop more advanced oxidation methods for PAN precursor... -
Carbon nanotubes synthesis using diffusion and premixed flame methods: a review
Garima Mittal, Vivek Dhand, Kyong Yop Rhee, Hyeon-Ju Kim and Dong Ho Jung 한국탄소학회 Carbon Letters 10 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 1 1-10 (10 pages)
In recent years, flame synthesis has absorbed a great deal of attention as a combustion method for the production of metal oxide nanoparticles, carbon nanotubes, and other related carbon nanostructures, over the existing conventional methods. Flame synthesis is an energyefficient, scalable, cost-effective, rapid and continuous process, where flame provides the necessary chemical species for the nucleation of carbon structures (feed stock or precursor) and the energy for the production of carbon... -
Effects of phosphorus content and operating temperature on the electrochemical performance of phosphorus-doped soft carbons
Eun Hee Kim and Yongju Jung 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 7 277-281 (5 pages)
A series of high capacity soft carbons with different phosphorus contents were successfully prepared by carbonizing petroleum cokes treated with hypophosphorous acid at 900°C. The effect of phosphorus content on the electrochemical performance of the soft carbons was extensively investigated. The P-doped soft carbons exhibited greatly enhanced discharge capacities and outstanding rate capabilities with increasing phosphorus content. In addition, the influence of temperature on the... -
Properties of multi-walled carbon nanotube reinforced epoxy composites fabricated by using sonication and shear mixing
Min Ye Koo, Hon Chung Shin, Won-Seok Kim and Gyo Woo Lee 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 4 255-261 (7 pages)
Multi-walled carbon nanotube reinforced epoxy composites were fabricated using shear mixing and sonication. The mechanical, viscoelastic, thermal, and electrical properties of the fabricated specimens were measured and evaluated. From the images and the results of the measurements of tensile strengths, the specimens having 0.6 wt% nanotube content showed better dispersion and higher strength than those of the other specimens. The Young’s moduli of the specimens increased as the nanotube filler...


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