- 공심법과 (Sr-Ti)수산염에 의한 고순도의 $SrTiO_3$ 합성에 관한 연구
- ㆍ 저자명
- 이종권,이병하
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1983년|20권 2호|pp.107-114 (8 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Formation of Strontium titanate from the products of coprecipitation takes place at 110$0^{circ}C$ which is 200-30$0^{circ}C$ lower than that from mechanical mixtures of $SrCO_3$ and $TiO_2$. This is apparently due to the nature of the compounds formed by the reaction of mixtures of aqueous solutions of $SrCl_2$ and $TiCl_4$ with an ammoniacal solution of ammoni-um carbonate and ammonium hydroxide. A procedure is described for preparing strontium titanyl oxalate tetrahydrate in the several mole ratio of $TiCl_4$ to $SrCl_2$. STrontium titanyl oxalates decompose to titanate at elevated temperature. The coprecipitates and the fired specimen were subjected to examined thermal and X-ray analyses and microstruc-ture by SEM.