기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
Calculation of NMR Shift in Paramagnetic System when the Threefold Axis is Chosen as the Quantization Axis (Ⅲ). The NMR Shift for 3d$^2$ System in a Strong Crystal Field of Octahedral Symmetry
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • Calculation of NMR Shift in Paramagnetic System when the Threefold Axis is Chosen as the Quantization Axis (Ⅲ). The NMR Shift for 3d$^2$ System in a Strong Crystal Field of Octahedral Symmetry
  • Calculation of NMR Shift in Paramagnetic System when the Threefold Axis is Chosen as the Quantization Axis (Ⅲ). The NMR Shift for 3d$^2$ System in a Strong Crystal Field of Octahedral Symmetry
저자명
Ahn. Sang Woon,Oh. Se Woong,Lee. Kee Hag
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1984년|5권 3호|pp.93-97 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

A general expression using the nonmultipole expansion method is derived for the NMR shift arising from 3d electron angular momentum and the 3d electron spin dipolar-nuclear spin angular momentum interactions for a 3$d^2$ system in a strong crystal field environment of octahedral symmetry when the threefold axis is chosen as the quantization axis. The NMR shift is separated to the contribution of constant, $1/R^5;and;1/R^7$ terms and compared with the multipolar terms. We find that $1/R^5$ term contributes dominantly to the NMR shift but the contribution of $1/R^7$<TEX> term may not be negligible. It is also found that the exact values of the NMR shift are in agreement with the multipolar results for distances larger than 0.35 nm.