To develope good slip and microstructure of Si3N4 the knowledge of the interaction of particles in liquid systems is required. In this work polyethyleneimines was tested as a stabilizer for Si3N4-water system. The stability of slip dispersed with polyethyleneimines was good over a wide range of pH and concentrated slips with low viscosity could be cast. This work comprises a systematic investigation including determination of electrical mobility in order to estimate the particle surface charge, determination of sedimentation rate, as well as measurements of the viscosity as a function of dispersants, pH and shear rates. The influence of deflocculation on the microstructure of slip cast Si3N4 was discussed.