- 광전자 분광법으로 분석한 스테인레스 강 304의 산화 표면
- ㆍ 저자명
- 이경철,함경희,안운선
- ㆍ 간행물명
- 한국표면공학회지
- ㆍ 권/호정보
- 1991년|24권 3호|pp.144-150 (7 pages)
- ㆍ 발행정보
- 한국표면공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The stainless steel 304 oxidized at $70^{circ}C$ in 2.5M CrO3/5.0M H2SO4 solution and at $200^{circ}C$ , $300^{circ}C$, and $400^{circ}C$ in the air are analyzed with X-ray Photoelectron Spectroscopy (XPS) to obtain depth composition profile of the surface region. It is confirmed that the surface region has a quite different composition from that of the bulk. This is due to a difference in the outward diffusion rates of the oxidized species in the surface region. The order of diffusion rates is Fe > Cr > Ni in the experimental temperature range. In spite of the inferior rate of diffusion, Cr is enriched in the surface when it is oxidized in the CrO3/H2SO4 solution. This is due to preferential dissolution of oxidized Fe.