The problem of natural convection from a vertical fin is solved by coupling the thermal diffusion equation in the fin to the constitutive equations of the ambient medium involving the radiation of the medium. The analysis is accomplished by employing an integral method. The governing equations for the problem are solved by shooting method based on the Runge-Kutta Scheme at Pr= 0.7. For the range of values of the fin parameter and the radiation-conduction parameter in the analysis, the numerical results show that the radiation effects play an important role in the heat transfer and enhance the heat transfer.