- MTS의 열분해를 이용한 $eta$-SiC의 화학증착 및 Excess C 공급원의 영향
- ㆍ 저자명
- 최병진,박병옥,김대룡
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1993년|30권 1호|pp.46-54 (9 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
$eta$-SiC was chemically vapor deposited by pyrolysis of MTS+H2 gas mixture. The experiments were conducted in the temperature range of 1100~150$0^{circ}C$ with a r.f. induction furnace under atmospheric pressure. The IR, XRD, EDS and AES analysis revealed that the free Si was always codeposited with SiC below 140$0^{circ}C$, regardless of the total flow rate and MTS concentration, whereas $eta$-SiC single phase was deposited at 150$0^{circ}C$. C3H8 or CH2Cl2 as an excess C sources, was supplied with MTS in order to obtain stoichiometric SiC at low temperature. With the addition of C3H8 or CH2Cl2, the deposition rate was increased and $eta$-SiC single phase could be deposited even at temperature as low as 110$0^{circ}C$. In the absence of C3H8 or CH2Cl2, the microhardness of the layer was quite low (<HV2000) becuase of codeposited free Si, with propane addition, however, it reached up to inherent SiC value ( HV3000).