- 졸-겔법에 의한 알루미나 화이버의 ${gamma}-LiAlO_2$ 코팅
- ㆍ 저자명
- 현상훈,홍성안,김완식,신현철
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1994년|31권 11호|pp.1271-1282 (12 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The surface of commercial alumina fibers used for reinforcing the MCFC matrix has been coated with ${gamma}$-LiAlO2 being the same material as the matrix, by the sol-gel method in order to enhance the corrosion resistivity of alumina fibers. Stable LiAlO2 complex polymeric sols for coating was synthesized by mixing aluminum alkoxide polymeric sols with LiNO3 solution. It was found that the LiAlO2 polymeric sol prepared by adding the mixed chelate of acethylacetone and triethanolamine (the mole ratio of AA/TEA = 0.125/0.75) to the 1 mole of the aluminum alkoxide had the excellent stability and coating behavior. The crystalline structure of the dried gel from the ${gamma}$-LiAlO2 sol was completely transformed into the ${gamma}$-LiAlO2 at $600^{circ}C$. The optimum viscosity of the sol for coating the alumina long fibers was 30~40 cP, while it was 12~20 cP in case of the short fiber coating. The ${gamma}$-LiAlO2 coated alumina fibers without defects fully densified when heat-treated at 120$0^{circ}C$.