- 전하적정법에 의한 $(Mg_{0.29}Fe_{0.71})_{3-}deltaO_4$ 훼라이트의 Nonstoichiometry$(delta)$와 상안정 영역 결정
- ㆍ 저자명
- 강선호,유한일,강대석,유병두
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1994년|31권 12호|pp.1491-1500 (10 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Nonstoichiometry($delta$) and the phase stability region of a ferrite spinel (Mg0.29Fe0.71)3-$delta$O4 have been investigated by a coulometric titration method as a function of temperature(T) and oxygen partial pressure(Po2). It has been found that the spinel is thermodynamically stable in the ranges -8.0$leq$log(PO2/atm)$leq$-2.4, -7.0$leq$log(PO2/atm)$leq$-1.7 respectvely at 100$0^{circ}C$. The nonstoichiometry extends over the ranges of -0.004$leq$$delta$$leq$0.007, -0.008$leq$$delta$$leq$0.006, -0.033$leq$$delta$$leq$0.004 at 100$0^{circ}C$, 120$0^{circ}C$, respectvely. The observed PO2-dependence of $delta$ suggests that the majority ionic defects are cation interstitials in the low PO2 region and cation vacancies in the high PO2 region.