- 졸-겔법에 의한 지르콘$(ZrSiO_4)$ 분말 합성 -재분쇄(Milling)에 대한 효과-
- ㆍ 저자명
- 신용철,신대용,한상목,남인탁
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1995년|32권 7호|pp.853-857 (5 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
ZrSiO4 powders were prepared from partially hydrolyzed solution of Si(OC2H5)4 and ZrOCl2.8H2O solution by the sol-gel method and formation rate of ZrSiO4 on the reaction parameter was investigated. In order to prepare homogeneous ZrSiO4 precursor gels, the H2O/Si(OC2H5)4 molar ratio of about 2, the pH of the ZrOCl2.8H2O solution fo about 4 and stirring time of the mixed solutions of about 2 hrs were appropriate. Formation of temperature of ZrSiO4 reduced about 15$0^{circ}C$ by milling and formation of ZrSiO4 at 1300~135$0^{circ}C$ showed an accelerative increase through the hedvall effect by silica.