- 인산염계 다공질 결정화 유리에 관한 연구
- ㆍ 저자명
- 박용완,현부성,김태호
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1995년|32권 7호|pp.858-864 (7 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
A porous glass-ceramics body was prepared in the phosphate system. The glass composition of 47.2CaO-22.2TiO2-30.6P2O5 (mol%) containing a few weight percent of ZrO2 was suitable for a mother glass of a porous glass-ceramics. The dense glass-ceramics body was made by a two-step heat treatment of the mother glass. The crystalline phases of the glass-ceramics were $eta$-Ca3(PO4)2 and CaTi4(PO4)6. The $eta$-Ca3(PO4)2 phase could be selectively leached out with HCl solution and thus a crystalline $eta$-Ca3(PO4)2 skeleton was remained. The dimension and shape of the porous glass-ceramics were nearly the same as the those of the first formed glass. The specific surface area and average proe radius of the porous glass-ceramics were 19$m^2$/g and 22 nm, respectively.