Flow times of the groundwater in the gneiss near Samkwang mine in Korea were estimated through the development of a mathematical model, the field hydraulic tests, and the analysis of tritium concentration of the groundwater and rainfall sampled in the study positions. Results of this study we as follows: (1) The mathematical model to calculate the age of groundwater was developed considering the tritium concentrations of rainfall precipitated in the studied area for period 1961 to 1993. (2) The ages of the groundwater in the tunnel 44, 92, 102, and 205 m below the surface were estimated at 2, 0, 4.0, 4.5, and 9.0 years, respectively. These results were verified by the data on the tritium concentrations of the groundwater in the tunnel for period 1991 to 1993.