- 전자 및 이온 전도성 $CeO_2-Sm_2O_3$ 고체 전해질 막의 합성 및 응용
- ㆍ 저자명
- 현상훈,권재환,김승구,김계태
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1998년|35권 4호|pp.355-363 (9 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The oxygen flux of SDC ($Sm_2O_3;doped;CeO_2$) solid electrolyte membranes with electronic and oxygen ion-ic conductivities has been investigated as a basic research in order to develop the conversion process of na-tural gas to syngas using the ceramic membrane reactor. Tube type membranes(1 mm thickness) were fa-bricated by slip casting of SDC powders prepared by the oxalate coprecipitaion method. Dense oxygen per-meation membranes(0.1 mm thickness) could be synthesized via sintering at $1450^{circ}C$ for 2h and their re-lative density was over 95% The oxygen flux through SDC membranes doped 20mol% $Sm_15$ was about $1.13{ imes}10^{-5};mol/m_2{cdot}sec$ at low temperature around $800^{circ}C$. In addition the SDC membranes showed a good thermaal stability for a long period of service.