In the gasoline engine of fuel injection type, atomization of fuel droplet and its distribution has directly influenced the performance of engine and harmful emission. To investigate atomization characteristics of fuel spray, in this paper fuel spray of air-assisted injector is observed at the various initial conditions of ambient air temperature and air assisted pressure. Behavior of fuel spray is photographed with microscopic visualization system. The SMD of fuel droplet is measured with PMAS (Particle Motion Analysis System). The effect of air-assisted pressure and temperature of ambient air resulted in the decrement of SMD and its variation. Finally, It was found that It was found that from spray angle at the two-hole injector had measured $20{pm}4$ degree the result of photographs by shadow graphy. The mean diameter of suns decreased and the of droplets increased with increasing the temperature in the spray fields by the results of PMAS measurement. It was found that the characteristics of sprays became finer by increasing the temperature of spray fields about 373K without the delivery of air-assistance.