The diesel vehicle is relatively superior to gasoline vehicle on the fuel consumption, durability and combustion efficiency. However, exhaust emission from diesel vehicle are known to be harmful to human health and environment. The treatment technologies for the diesel exhaust gases are classified as replacement of fuel, quality control of diesel fuel, improvement of engine and aftertreatment system. The most effective for the treatment technology is known to be aftertreatment system, and this research is continuously conducted by many groups. The DOC system has many advantages of reducing particulates and harmful gaseous substances such as CO. HC. Moreover, it is simple in device structure, relatively low cost, and easy to install witout retrofitting the vehicle. In this study, experiment were conducted to analyze the effects on factors of oxidation characteristics and conversion efficiency of DOC. In experiment, test was conducted to estimate engine emission in 11,000cc diesel engine which was equipped with DOC.