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Influence of Cu Doping and Heat Treatments on the Physical Properties of ZnTe Films
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  • Influence of Cu Doping and Heat Treatments on the Physical Properties of ZnTe Films
  • Influence of Cu Doping and Heat Treatments on the Physical Properties of ZnTe Films
저자명
최동일,윤세왕,김동환,Choe. Dong-Il,Yun. Se-Wang,Kim. Dong-Hwan
간행물명
한국재료학회지
권/호정보
1999년|9권 2호|pp.173-180 (8 pages)
발행정보
한국재료학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Thermally evaporated ZnTe films were investigated as a back contact material for CdS/CdTe solar cells. Two deposition methods, coevaporation and double-layer methods, were used for Cu doping in ZnTe films. ZnTe layers (0.2$mu extrm{m}$ thick) were deposited either on glass or on CdS/CdTe substrates without intentional heating of the substrates. Post-deposition annealing was performed at 200,300 and $400^{circ}C$ for 3,6 and 9 minutes, respectively. Band gap of 2.2eV was measured for both undoped and doped films and a slight change in the shape of absorption spectra was observed in Cu-doped samples after annealing at $400^{circ}C$. The resistivity of as-deposited ZnTe decreased from 10ulcorner~10ulcornerΩcm down to 10ulcornerΩcm as Cu concentration increased from 0 to 14 at.%. There was not a noticeable change in less of annealing temperature up to $300^{circ}C$ whereas films annealed at $400^{circ}C$ revealed hexagonal (101) orientations as well. Some of Cu-doped ZnTe revealed x-ray diffraction (XRD) peaks related with CuulcornerTe(x=1.75~2). Grain growth was observed from about 20nm in as-deposited films to 50nm after annealing at $400^{circ}C$ by scanning electron microscopy (SEM). Cu distribution in ZnTe films was not uniform according to Auger electron spectroscopy (AES) measurements.