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순환식 반응기에서 $TiO_{2}$ 광촉매를 이용한 Chromium(VI)의 제거에 미치는 영향인자에 대한 연구
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  • 순환식 반응기에서 $TiO_{2}$ 광촉매를 이용한 Chromium(VI)의 제거에 미치는 영향인자에 대한 연구
저자명
김현용,조일형,이소진,기원주,이홍근,Kim. Hyun-Yong,Cho. Il-Hyoung,Lee. So-Jin,Ki. Won-Ju,Lee. Hong-Keun
간행물명
한국환경위생학회지
권/호정보
1999년|25권 3호|pp.64-69 (6 pages)
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한국환경보건학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This study was carried out the removal of Cr(VI) which was known to the toxic pollutant in industry using the process of UV and TiO$_2$ photocatalyst in a circular type reactor. In this experiment, the series of photocatalytic process for the removal of Cr(VI) has been selected as a model reaction in a circular type reactor in order to obtain the basic data on the influence of various experimental parameters such as circulation flow rate, pH of solution, initial Cr(VI) light illumination and TiO$_2$ dosage, and salicylic acid concentration. The results of this study were as follows; 1. With both UV light illumination and TiO$_2$ present, Cr(VI) was more effectively eliminated than with either UV or TiO$_2$ alone. 2. As the circulation flow rate of solution increased, the removal efficiency of Cr(VI) was increased. However, over 2.4 l/min of circulation flow rate, the efficiency wa limited. 3. A increase in the photocatalytic removal of Cr(VI) was noticed with decreasing pH. 4. An increase in the photocatalytic removal of Cr(VI) was noticed with decreasing Initial Cr(VI) concentration and first order kinetics was observed from the result at different initial concentration of Cr(VI). 5. Photocatalytic removal efficiency of Cr(VI) increased with increasing TiO$_2$ dosage. However, over 1.0 g/l of TiO$_2$ dosage, the efficiency reached a plateau. 6. As low concentration of saliculic acid were added, there was an increase in the removal efficiency of Cr(VI). However, over 300 mg/l of salicylic acid, the efficiecy was decreased. It eas found that application of photocatalysis to water treatment that contains both Cr(VI) and salicylic acid was possible.