This paper presents the effects of initial pressure of mixture on CO, $CO_2$ and NOx emissions in constant volume combustion chamber. The CO, $CO_2,O_2,N_2$ concentrations in the chamber are determined by thermal conductivity detection (Gas-chromatograph) wile the NOx concentration is measured by chemiluminescent detection (NOx Analyser). Methane-air mixture is used as premixed fuel and the measurements are taken with equivalence ratios($phi$) varing from 0.6 to 1.3, and initial pressures of methane-air mixture varing from 0.1MPa to 0.8MPa in constant volume combustion chamber. The NOx concentration steadily increases with increasing equivalence ratio, peaks in lean flame ($phi$=0.85~0.9), and then rapidly decreases. However, as the initial pressure of mixture is increased, the equivalence ratio corresponding to the point of peak [NOx] shifts towards leaner conditions. This is caused by a similar shift in the peak [CH], which is caused by the variation with pressure and equivalence ratio of the rate of CH production from $CH_2$ and OH. The maximum combustion pressure peaks at $phi$ =1.05 and the $CO_2$ concentration peaks at $phi$=0.95~1.0 while the CO concentration rises sharply at the condition of fuel-rich mixtures. This is caused by complete combustion at $phi$=0.95