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Mechanism of Morphological Transition from Lamellar/Perforated Layer to Gyroid Phases
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  • Mechanism of Morphological Transition from Lamellar/Perforated Layer to Gyroid Phases
  • Mechanism of Morphological Transition from Lamellar/Perforated Layer to Gyroid Phases
저자명
Ahn. Jong-Hyun,Zin. Wang-Cheol
간행물명
Macromolecular research
권/호정보
2003년|11권 3호|pp.152-156 (5 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

We investigated epitaxial relations of phase transitions between the lamellar (L), hexagonally perforated layers (HPL), and gyroid (G) morphologies in styrene-isoprene diblock copolymer (PSI) and polyisoprene (PI)/PSI blend using rheology and small angle X-ray scattering (SAXS) techniques. In HPLlongrightarrowG transitions, six spot patterns of G phase were observed in two-dimensitional SAXS pattern. On the other hand, in direct L-longrightarrowG transition without appearance of HPL phase, the polydomain patterns of G phase were observed. From present study, it was understood that direct LlongrightarrowG transition of blend may be suppressed by high-energy barrier of transition and mismatches in domain orientation between epitaxially related lattice planes.