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Gas Separation Properties of 6FDA-Based Polyimide Membranes with a Polar Group
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  • Gas Separation Properties of 6FDA-Based Polyimide Membranes with a Polar Group
  • Gas Separation Properties of 6FDA-Based Polyimide Membranes with a Polar Group
저자명
Park. Sang-Hee,Kim. Kwang-Je,So. Won-Wook,Moon. Sang-Jin,Lee. Soo-Bok
간행물명
Macromolecular research
권/호정보
2003년|11권 3호|pp.157-162 (6 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

6FDA-based polyimides were prepared from the thermal imidization reaction of 6FDA with diamines of BAPAF, DAP, and DABA having a polar group of hydroxyL or carboxyl. Properties of the dense polyimide membranes were characterized and their gas permeation properties for H$_2$, $CO_2$, $O_2$, $N_2$, and CH$_4$ were investigated. Permeabilities, diffusion coefficients and diffusivity selectivities of polar group-containing polyimide membranes including 6FDA-BAPAF, 6FDA-DAP, and 6FDA-DABA polymer for the gases did not change largely. The separation properties of 6FDA-TrMPD polyimide membrane used as a reference polymer were compared with those of the polyimide membranes mentioned above. It was found that the polyimides of 6FDA-BAPAF, 6FDA-DAP, and 6FDA-DABA, which were soluble in alcohol or/and 2-methoxyethanol, could be applicable to the preparation of a dense composite membrane by dip-coating method.