- 유연한 연결기를 갖는 새로운 방향족 Polyformamidine의 합성과 성질
- Preparation and Properties of Novel Aromatic Polyformamidines Haying Flexible Linkages
- ㆍ 저자명
- 정화진
- ㆍ 간행물명
- 韓國纖維工學會誌
- ㆍ 권/호정보
- 2003년|40권 5호|pp.393-400 (8 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
New aromatic polyformamidines were prepared by reaction of triethyl orthoformate with aromatic diamines containing various flexible linkages such as ether, isopropylidene, and hexafluoroisopropylidene between aromatic rings in N.N-dimethylsufoxide(DMSO) via high temperature solution polycondensation. The proposed structures of the resultant polymers were confirmed by elemental analysis, IR- and $^1$H-NMR spectroscopy. These polymers had inherent viscosities up to 0.42 dL/g, and most of them could be readily soluble in aprotic amide solvents including N-methyl-2-pyrrolidone, N,N-dimethylacetamide, N,N-dimethylformamide, and DMSO at room temperature. Wide angle X-ray diffractograms(WAXD) revealed that the polymers were partially crystalline or amorphous. The glass transition temperatures of the polymers could be determined by differential scanning calorimetry (DSC) and were in the range of 118∼245 $^{circ}C$. Thermogravimetric analysis(TGA) indicated that the polymers are stable in nitrogen up to 300 $^{circ}C$, and 10% weight loss occurred in the temperature range of 320∼395 $^{circ}C$ in air.