풀러렌[$C_{60},;C_{70}$]을 benzoylperoxide, trichloroisocyanuric acid, methyltrioxorhenium(VII), iodosobenzene 그리고 phosphorous pentoxide 등의 산화제를 사용하여 상온, 초음파 조건에서 풀러렌 산화물을 제조하였다. MALDI-TOF MS, UV-VIS 그리고 HPLC를 사용하여 분석한 결과 생성된 풀러렌 산화물은 [$C_{60}(O)_n$], ($n=1{sim}3$ 또는 n=1)과 [$C_{70}(O)_n$], ($n=1{sim}2$ 또는 n=1)임을 알 수 있었다. 한편, 동일한 실험 조건에서 $C_{60}$ 반응속도는 $C_{70}$ 보다 높았다.
Synthesis of fullerene oxides by fullerenes [$C_{60},;C_{70}$] and several oxidants such as benzoylperoxide, trichloroisocyanuric acid, methyltrioxorhenium(VII), iodosobenzene, phosphorous pentoxide take place under ultrasonic condition at room temperature. The MALDI-TOF MS,UV-visible spectra and HPLC analysis confirmed that the products of fullerenes oxidation are [$C_{60}(O)_n$], ($n=1{sim}3$ or n=1) and [$C_{70}(O)_n$], ($n=1{sim}2$ or n=1). As compared with the reactivity of epoxidation of fullerenes [$C_{60},;C_{70}$], the reaction rate of $C_{70}$ was lower than that of $C_{60}$ under same reaction condition.
