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A Study on Existing Rubber Elasticity Theories for Stress-Strain Behavior of Rubber-like Networks
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  • A Study on Existing Rubber Elasticity Theories for Stress-Strain Behavior of Rubber-like Networks
  • A Study on Existing Rubber Elasticity Theories for Stress-Strain Behavior of Rubber-like Networks
저자명
Meissner. B.
간행물명
엘라스토머
권/호정보
2003년|38권 2호|pp.157-166 (10 pages)
발행정보
한국고무학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

The Edwards-Vilgis slip-link theory and the Kaliske-Heinrich extended tube theory were tested experimentally using published experimental data on networks of natural and isoprene rubber and on polysiloxane networks. All parameters were adjusted to achieve an optimum fit. The data description obtained with the EV theory is not satisfactory and the parameter values tend to lie outside their reasonably expected range. But for the region of low strains, the Kaliske-Heinrich theory offers a satisfactorily accurate data description which is able to serve for practical purposes. Its crosslink term, however, is based on approximations which lead to a questionable prediction and values determined for the exponent in the entanglement term lie outside the range expected by the KH model. Thus, the title question cannot be given a positive answer. Conclusions published earlier that the trapped entanglements contribute both to the crosslink and constraint (entanglement) term are supported by the present data analysis. Experimental equibiaxial data on hydrocarbon networks do not show any maximum on their stretch ratio dependence, contrary to the predictions of molecular theories. The stretch ratio dependences of relative reduced stresses do not sensitively reflect differences in the chemical nature of the chain backbone (hydrocarbon vs. siloxane) and in the crosslinking method (end-linking vs. random crosslinking).