- 부양가스응축법에 의해 제조된 철산화물 나노 분말의 자기적 특성연구
- ㆍ 저자명
- 엄영랑,김흥회,이창규
- ㆍ 간행물명
- 한국분말야금학회지
- ㆍ 권/호정보
- 2004년|11권 1호|pp.50-54 (5 pages)
- ㆍ 발행정보
- 한국분말야금학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Nanoparticles of iron oxides have been prepared by the levitational gas condensation (LGC) method, and their structural and magnetic properties were studied by XRD, TEM and Mossbauer spectroscopy. Fe clusters were evaporated from a surface of the levitated liquid Fe droplet and then condensed into nanoparticles of iron oxide with particle size of 14 to 30 nm in a chamber filled with mixtures of Ar and $O_2$ gases. It was found that the phase transition from both $gamma$-$Fe_2O_3$ and $alpha$-Fe to $Fe_3O_4$, which was evaluated from the results of Mossbauer spectra, strongly depended on the $O_2$ flow rate. As a result, $gamma$-$Fe_2O_3$ was synthesized under the $O_2$ flow rate of 0.1$leq$$Vo_2$(Vmin)$leq$0.15, whereas $Fe_3O_4$ was synthesized under the $O_2$, flow rate of 0.15$leq$$Vo_2$(Vmin)$leq$0.2.