The emission control of automobile has been intensified as a part of the countermeasure to decrease air pollution in the world. As the cars with an alternative fuel starts to get into the spotlight, the cars with low emission has been introduced and exhaust gas regulation forced in this country. These days, LPG vehicles, which infrastructure of fuel was already built up, and CNG vehicles are recognized for alternative fuel cars in this country. In this study, the constant volume combustion chamber was manufactured and used for experiments to obtain the combustion characteristics of propane mixture. The combustion characteristics was analyzed, with the change of supply conditions of propane fuel. Inside the combustion chamber, the maximum temperature increase with the initial pressure is going up. The burning velocity also seems to have the same characteristic as the temperature. However, the heat flux do not change much according to the theoretical correct mixture but it changes with the various initial temperature of the combustion chamber.