An experimental study was performed to investigate the liquid breakup and atomization characteristics in electrohydrodynamic atomization according to the changing of experimental parameters such as nozzle size, fluid flow, and electrical intensity. An original electrohydrodynamic atomizer equipment was designed and manufactured for the analysis of spray visualization and the exploration of relationship between applied power and the behavior of liquid atomization. The image processing technique by using the back-illumination method was applied to visualize the distilled liquid breakup process and to examine the variation of the droplet size distribution. The results show that the spray modes of electrohydrodynamic atomization are closelyconnected by the strength of the electric stresses at the surface of the liquid film and the kinetic energy of the liquid jet leaving the needle tip.