The electro rheological behavior of the hollow polyaniline pimelate suspension in silicone oil was investigated. Hollow polyaniline pimelate suspension showed a typical ER response (Bingham flow behavior) upon application of an electric field. The shear stress for the suspension exhibited the dependence with a factor equals to 0.84 power on the electric field. The experimental results for the hollow polyaniline pimelate suspension correlated with the conduction models of Tang et al., and this suspension behaved as an ER fluid.