The electrical insulation design and withstanding test of mini-model coils for 600 kJ class conduction cooled high temperature superconducting magnetic energy storage (HTS SMES) have been studied in this paper. The high voltage is generated to both ends of magnet of HTS SMES by quench or energy discharge. Therefore, the insulation design of the high voltage needs for commercialization, stability, reliability and so on. In this study, we analyzed the insulation composition of a HTS SMES, and investigated about the insulation characteristics of the materials such as Kapton, AIN and vacuum in cryogenic temperature. Base on these results, the insulation design for 600 kJ conduction cooled HTS SMES was performed. The mini-model was manufactured by the insulation design, and the insulation test was carried out using the mini-model.