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DCA-MOD 방법으로 제조된 YBCO 박막의 미세조직에 미치는 열처리 효과
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  • DCA-MOD 방법으로 제조된 YBCO 박막의 미세조직에 미치는 열처리 효과
  • Effects of Heat Treatments on the Microstructure of YBCO Films Prepared by DCA-MOD Method
저자명
김병주,김혜진,조한우,유석구,유정희,이희균,홍계원,Kim. Byeong-Joo,Kim. Hye-Jin,Cho. Han-Woo,Yu. Seok-Koo,Ryu. Jung-Hee,Lee. Hee-Gyoun,Hong. Gye-Won
간행물명
Progress in superconductivity
권/호정보
2007년|9권 1호|pp.96-101 (6 pages)
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한국초전도학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

[ $YBa_2Cu_3O_{7-{delta}}$ ] films have been prepared on $LaAlO_3$ (100) single-crystal substrates by a metalorganic deposition using dichloroacetate precursors (DCA-MOD). Calcination conditions were varied in order to optimize the microstructure and the superconducting properties of YBCO film. Coated films were calcined at various temperatures ranging from $400{sim}700^{circ}C$ in flowing humid oxygen atmosphere. Ramping rate to calcination tempertures was $2.22^{circ}C/min$. Conversion heat treatment was performed at $800^{circ}C$ for 2 h in flowing Ar gas containing 1000 ppm oxygen with a humidity of 9.45%. Observations of surface and cross sectional SEM microstructure showed that the particle size in the calcined film increased in the range of 100-200 nm with heating rate and the calcination temperature. SEM EDS analysis showed that 13 a/o of chlorine was contained in the calcined film. It was also observed that the porosity increased with the heating rate and temperature. Porous microstructure was developed when YBCO films were prepared using porous calcined film. Dense microstructure and high $J_c$ over $1;MA/cm^2$ was obtained when calcination was carried out at the temperature of $500^{circ}C$ with a heating rate of $2.22^{circ}C/min$.