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Sintering and Consolidation of Silver Nanoparticles Printed on Polyimide Substrate Films
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  • Sintering and Consolidation of Silver Nanoparticles Printed on Polyimide Substrate Films
  • Sintering and Consolidation of Silver Nanoparticles Printed on Polyimide Substrate Films
저자명
Yoon. Sang-Hwa,Lee. Jun-Ho,Lee. Pyoung-Chan,Nam. Jae-Do,Jung. Hyun-Chul,Oh. Yong-Soo,Kim. Tae-Sung,Lee. Young-Kwan
간행물명
Macromolecular research
권/호정보
2009년|17권 8호|pp.568-574 (7 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

We investigated the sintering and consolidation phenomena of silver nanoparticles under various thermal treatment conditions when they were patterned by a contact printing technique on polyimide substrate films. The sintering of metastable silver nanoparticles commenced at 180 $^{circ}C$, where the point necks were formed at the contact points of the nanoparticles to reduce the overall surface area and the overall surface energy. As the temperature was increased up to 250 $^{circ}C$, silver atoms diffused from the grain boundaries at the intersections and continued to deposit on the interior surface of the pores, thereby filling up the remaining space. When the consolidation temperature exceeded 270 $^{circ}C$, the capillary force between the spherical silver particles and polyimide flat surface induced the permanent deformation of the polyimide films, leaving crater-shaped indentation marks. The bonding force between the patterned silver metal and polyimide substrate was greatly increased by the heat treatment temperature and the mechanical interlocking by the metal particle indentation.