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Copolymerization of L-Lactide and ${varepsilon}$-Caprolactone in Supercritical Fluid
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  • Copolymerization of L-Lactide and ${varepsilon}$-Caprolactone in Supercritical Fluid
  • Copolymerization of L-Lactide and ${varepsilon}$-Caprolactone in Supercritical Fluid
저자명
Prabowo. Benedictus,Choi. Dong-Hoon,Kim. Soo-Hyun
간행물명
Macromolecular research
권/호정보
2009년|17권 8호|pp.575-579 (5 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Copolymerization of L-lactide and s-caprolactone initiated by tin (II) octoate (Sn(Oct)$_2$) was carried out in supercritical chlorodifluoromethane (R22) with varying reaction conditions (time and temperature) and amounts of monomer and catalyst, under a pressure of 250 bar. The optimum conditions were a reaction time of 10 h and a temperature of 130 $^{circ}C$, which is similar to the temperature used in bulk copolymerization system. The conversion increased from 56% to 76% by increasing the reaction time from 1 to 10 h. The molecular weight also increased to 75,900 g.mol$^{-1}$ over the same period, while the increased monomer concentration resulted in a high molecular weight of 86,400 g.mol$^{-1}$ and a monomer conversion of 84%. Raising the reaction temperature from 90 to 130 $^{circ}C$ increased the monomer conversion as well as the poly-L-lactide-co-${varepsilon}$-caprolactone (PLCL) molecular weight. The variation on the stannous octoate catalyst suggested that less catalyst would decrease the caprolactone content of the polymer.